Increases of wet deposition at remote sites in Japan from 1991 to 2009     

Kyo Kitayama  Sinya Seto  Manabu Sato  Hiroshi Hara 《Journal of Atmospheric Chemistry》2012,69(1):33-46

Temporal trends in wet deposition of major ions were explored at nationwide remote sites in Japan from April 1991 to March 2009 by using the seasonal Kendall slope estimator and the nonparametric seasonal Kendall test. For the trend analysis, datasets from eight remote sites (Rishiri, Echizenmisaki, Oki, Ogasawara, Shionomisaki, Goto, Yakushima, and Amami) were selected from the Japanese Acid Deposition Survey (JADS) conducted by the Ministry of the Environment. Deposition of H⁺ has been increasing at remote sites in Japan on a national scale. Significant (p????0.05) increases in H⁺ deposition were detected with changes of +3?C+9?%?year^?1 at seven sites, while insignificant increases were observed at one site. Depositions of non-sea salt (nss)-SO ₄ ^2? and NO ₃ ^? significantly increased at four and six sites, respectively, with changes of +1?C+3?%?year^?1. Significant increases in precipitation at four sites would have contributed to the increase in depositions of H⁺, nss-SO ₄ ^2? , and NO ₃ ^? . The emission trends of SO₂ and NO_x did not corresponded to the deposition trends of nss-SO ₄ ^2? and NO ₃ ^? . The different trends indicated that temporal variation of precipitation amount trend dominated the deposition trends.  相似文献   

Impact of land uses on heavy metal distribution in the Selenga River system in Mongolia   总被引：1，自引：0，他引：1  

Orgilbold Myangan  Masayuki Kawahigashi  Bolormaa Oyuntsetseg  Nobuhide Fujitake 《Environmental Earth Sciences》2017,76(9):346

The Selenga River contributes to 50% of the total inflow to Lake Baikal. Large tracts of the Selenga River Basin have been developed for industry, urbanization, mining, and agriculture, resulting in the release of suspended solids (SS) that affect downstream water quality and primary productivity. This study addressed SS as the main factor controlling pollutant transport and the primary indicator of land degradation in the Selenga River system. Tributaries with larger areas dedicated to agricultural use had higher SS concentrations, reaching 862 mg L^?1, especially during the high runoff and intensive cultivation season. Although the large SS flux was detected in the main river, the small tributaries were distinguished by high SS concentrations. The high SS concentration corresponded to widespread development in the watershed. Watersheds with high potential of SS release are sensitive to intensive land uses. SS in the river system had a constant elemental composition consisting mainly of Fe and Al oxides, indicating that surface soils were major constituents of the tributary SS. Three minor heavy metals (Zn, Cu, and Cr) appeared in high concentrations downstream of urban and mining areas (two- to sixfold increases), indicating that these contaminants are carried by SS. At two tributary junctions, the concentration of contaminants on the SS decreased due to a large influx of SS with low heavy metal contents. Changes in electric conductivity and pH at downstream of tributary junctions enhanced the sedimentation of SS and the removal of contaminants from the water phase after aggregation of the SS. Land use changes in the tributary watersheds are major controlling factors for the fate of contaminants in the river system.  相似文献   

Effects of sheens associated with offshore oil and gas development on the feather microstructure of pelagic seabirds     

Patrick D. O’Hara  Lora A. Morandin 《Marine pollution bulletin》2010,60(5):672-678

Operational discharges of hydrocarbons from maritime activities can have major cumulative impacts on marine ecosystems. Small quantities of oil (i.e., 10 ml) results in often lethally reduced thermoregulation in seabirds. Thin sheens of oil and drilling fluids form around offshore petroleum production structures from currently permissible operational discharges of hydrocarbons. Methodology was developed to measure feather microstructure impacts (amalgamation index or AI) associated with sheen exposure. We collected feather samples from two common North Atlantic species of seabirds; Common Murres (Uria aalge) and Dovekies (Alle alle). Impacts were compared after feather exposure to crude oil and synthetic lubricant sheens of varying thicknesses. Feather weight and microstructure changed significantly for both species after exposure to thin sheens of crude oil and synthetic drilling fluids. Thus, seabirds may be impacted by thin sheens forming around offshore petroleum production facilities from discharged produced water containing currently admissible concentrations of hydrocarbons.  相似文献   

A probabilistic approach to exposure risk assessment   总被引：1，自引：1，他引：0  

Crispin M. Mutshinda  Imoh Antai  Robert B. O’Hara 《Stochastic Environmental Research and Risk Assessment (SERRA)》2008,22(4):441-449

The introduction of hazardous substances into the environment has long been recognized as being a cause of several diseases in humans, wildlife, and plants. The damaging character of suspected contaminants is usually assessed via a “reject/retain” design with no explicit link between levels of exposure and intensities of the potential adverse health effects even though this connection may be important for the development of public health regulations that limit exposure to hazardous substances. Here, we propose a probabilistic approach to exposure risk assessment as a way around this typical flaw. We develop a Bayesian model using proximity to the source of an alleged contaminant as a surrogate for exposure. Subsequently, we carry out an experimental study based on simulated data to illustrate the model implementation with real world data. We also discuss a possible way of extending the model to accommodate potential heterogeneity in the spatial distribution of the focal disease.  相似文献   

Aluminum in the East China Sea and Okinawa Trough, marginal sea areas of the Western North Pacific     

Masayuki Minakawa  Yasunori Watanabe 《Journal of Oceanography》1998,54(6):629-640

The distribution of aluminum (Al) in seawater has been investigated in the continental slope and the Okinawa Trough areas of the East China Sea, which is one of the marginal seas in the western North Pacific Ocean. Aluminum concentration in waters over the slope and the Trough ranged from 5.6 to 25 nmol/kg in the surface layer (0–100 m), and had a minima of 1.1 nmol/kg between 400 and 500 m depth and ranged from 1.3 to 9.7 nmol/kg in the deep or bottom waters. Aluminum values were higher than in the surface waters of the central North Pacific, while minimum values were similar to levels in the intermediate or deep waters of the central North Pacific, except for the bottom water over the slope. This suggests that the high Al concentration in the surface reflects the large atmospheric input of Asian dust around the western side of the North Pacific region. On the continental slope, Al concentrations in the upper 500 m depth decreased slopeward. This horizontal gradient of Al can be explained from the combination of dilution by upwelling of Al-poor water originated from the North Pacific Intermediate Water (NPIW) which intrudes into the mid-depth of the Okinawa Trough and the scavenging of Al by biogenic particles in the continental slope zone.  相似文献   

Detrital zircon multi‐chronology,provenance, and low‐grade metamorphism of the Cretaceous Shimanto accretionary complex,eastern Shikoku,Southwest Japan: Tectonic evolution in response to igneous activity within a subduction zone          下载免费PDF全文

Hidetoshi Hara  Yoshihiro Nakamura  Kousuke Hara  Toshiyuki Kurihara  Hiroshi Mori  Hideki Iwano  Tohru Danhara  Shuhei Sakata  Takafumi Hirata 《Island Arc》2017,26(6)

Detrital zircon multi‐chronology combined with provenance and low‐grade metamorphism analyses enables the reinterpretation of the tectonic evolution of the Cretaceous Shimanto accretionary complex in Southwest Japan. Detrital zircon U–Pb ages and provenance analysis defines the depositional age of trench‐fill turbidites associated with igneous activity in provenance. Periods of low igneous activity are recorded by youngest single grain zircon U–Pb ages (YSG) that approximate or are older than the depositional ages obtained from radiolarian fossil‐bearing mudstone. Periods of intensive igneous activity recorded by youngest cluster U–Pb ages (YC1σ) that correspond to the younger limits of radiolarian ages. The YC1σ U–Pb ages obtained from sandstones within mélange units provide more accurate younger depositional ages than radiolarian ages derived from mudstone. Determining true depositional ages requires a combination of fossil data, detrital zircon ages, and provenance information. Fission‐track ages using zircons estimated YC1σ U–Pb ages are useful for assessing depositional and annealing ages for the low‐grade metamorphosed accretionary complex. These new dating presented here indicates the following tectonic history of the accretionary wedge. Evolution of the Shimanto accretionary complex from the Albian to the Turonian was caused by the subduction of the Izanagi plate, a process that supplied sediments via the erosion of Permian and Triassic to Early Jurassic granitic rocks and the eruption of minor amounts of Early Cretaceous intermediate volcanic rocks. The complex subsequently underwent intensive igneous activity from the Coniacian to the early Paleocene as a result of the subduction of a hot and young oceanic slab, such as the Kula–Pacific plate. Finally, the major out‐of‐sequence thrusts of the Fukase Fault and the Aki Tectonic Line formed after the middle Eocene, and this reactivation of the Shimanto accretionary complex as a result of the subduction of the Pacific plate.  相似文献   

Characterization of sulfate mineral deposits in central Thailand          下载免费PDF全文

Junichiro Kuroda  Hidetoshi Hara  Katsumi Ueno  Thasinee Charoentitirat  Teruyuki Maruoka  Takashi Miyazaki  Akira Miyahigashi  Stefano Lugli 《Island Arc》2017,26(2)

In this paper we present petrographic and geochemical data of sulfate mineral deposits in northeast Nakhon Sawan, central Thailand, and provide new constraints on their age. The deposits are made up mainly of strongly deformed nodular and massive gypsum in the upper part, and less deformed layered anhydrite in the lower part. They are intruded by andesitic dikes that contain Middle Triassic zircons (ca 240 Ma). These dikes are probably part of the regional magmatic activity of the Sukhothai Arc during the Early to Middle Triassic. Sulfur (δ³⁴S) and strontium (⁸⁷Sr/⁸⁶Sr) isotopic compositions of the sulfates range from 15.86 ‰ to 16.26 ‰ and from 0.70810 to 0.70817, respectively. Comparisons with the Phanerozoic seawater isotopic evolution curve indicate that those values are best explained by precipitation of the sulfates from Carboniferous seawater, in particular seawater of late Mississippian age (ca 326 Ma), and this would be consistent with previous studies of calcareous fossils in the limestones that crop out around this site. Our interpretation is that evaporitic gypsum was originally precipitated from hypersaline seawater on a shallow lagoon or shelf on the Khao Khwang Platform during the Serpukhovian, and that this gypsum changed to anhydrite during early burial. The anhydrite was then cut by andesitic dikes during the Middle Triassic, and more recently the upper part of which was rehydrated during exhumation to form secondary gypsum near the surface.  相似文献   

Recent and historical tsunami deposits from Lake Tokotan,eastern Hokkaido,Japan, inferred from nondestructive,grain size,and radioactive cesium analyses     

Shinozaki  Tetsuya  Sawai  Yuki  Ito  Kazumi  Hara  Junko  Matsumoto  Dan  Tanigawa  Koichiro  Pilarczyk  Jessica E. 《Natural Hazards》2020,103(1):713-730

Geological evidence of recent tsunamis from sediment samples collected from Lake Tokotan, a coastal lagoon in eastern Hokkaido, northern Japan, was detected using computed tomography (CT) and soft X-ray images, grain size, and radionuclide profiles. Initial field observations revealed that sediments had no discernable sedimentary structures at the top of the core. However, results of CT imaging, soft X-ray, and grain size analyses show evidence for three invisible sand layers that are intercalated with mud layers. These sand layers exhibit trends of landward fining and thinning. Furthermore, the distribution of sand layers was limited to the center and seaward parts of the lake. Vertical profiles of cesium and lead concentrations in combination with recent eyewitness accounts indicated that these sand layers are correlated with the 1973 Nemuro-oki, 1960 Chilean, and 1952 Tokachi-oki tsunami events. The deeper part of the sediment cores includes three volcanic ash layers and three prehistoric coarse sand layers. The prehistoric layers are correlated with unusually large tsunamis that were geologically identified in previous studies from eastern Hokkaido. These findings suggest that nondestructive techniques, in combination with radionuclide analysis, allow for detection of frequent but faint tsunami deposits. This technique allows for an improved understanding of the history of tsunami inundation in Lake Tokotan and of other locations for which stratigraphic evidence for faint tsunamis layers is not readily apparent from field assessments.

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Clean and safe supply of fish and shellfish to clear the HACCP regulation by use of clean and cold deep ocean water in Rausu, Hokkaido, Japan     

Masayuki Mac Takahashi Kazunori Yamashita 《中国海洋大学学报(英文版)》2005,4(3):219-223

For the supply of fish and shellfish to consumers in fresh condition, clean handling after catch from the sea is essential. According to HACCP （Hazard Analysis and Critical Control Points）, it is important to meet such requirement by keeping fish and shellfish under a certain low temperature and clean conditions after catching. The deep ocean water （DOW） characterized by low temperature and cleanliness has been chosen for fish and shellfish handlings, particularly for salmon, cod, and sea urchin in Town ＇Rausu＇ in Hokkaido, Japan. DOW below 2.9℃ of an amount of nearly 5 000 m^3 is planned to be pumped up every day from a depth of about 350 m, and temporarily stored in a large simulated tank on land. DOW is then supplied to fish boats through hydrants distributed throughout the harbor and used for keeping salmon in clean and cold conditions. Ice made from DOW is also used for lowering temperature if necessary. DOW and ice made from DOW are also used during the transportation of fish and shellfish. The entire system is scheduled to be completed by the summer of 2005.  相似文献   

The role of the grain boundary at chemical and isotopic fronts in marble during contact metamorphism     

Hideki Wada  Takamaru Ando  Masayuki Suzuki 《Contributions to Mineralogy and Petrology》1998,132(4):309-320

Carbon and oxygen isotopic profiles around a low pressure metasomatic wollastonite reaction front in a marble of the Hida metamorphic terrain, central Japan, display typical metamorphic fluid-enhanced isotopic zonations. Isotopic profiles obtained from detailed microscale analyses perpendicular to the chemical reaction front in calcite marble show that diffusion-enhanced isotopic exchange may control these profiles. Carbon and oxygen isotopic behaviour in grain boundaries is remarkably different. Oxygen isotopic troughs (¹⁸O depleted rims) around the calcite-grain boundaries are widely observed in this contact aureole, demonstrating that diffusion of oxygen in calcite grain boundary dominates over lattice diffusion in calcite. In contrast, no difference is observed in carbon isotopic profiles obtained from grain cores and rims. There is thus no specific role of the grain boundary for diffusion of carbonic species in the metamorphic fluid during transportation. Carbon chemical species such as CO₂ and CO₃ ions in metamorphic fluid migrate mainly through lattice diffusion. The carbon and oxygen isotope profiles may be modelled by diffusion into a semi-infinite medium. Empirically lattice diffusion of oxygen isotopes is almost six times faster than that of carbon isotopes, and oxygen grain-boundary diffusion is ten times faster than oxygen lattice diffusion. Oxygen isotopic results around the wollastonite vein indicate that migration of the metamorphic fluid into calcite marble was small and was parallel to the aquifer. From the stability of wollastonite and the attainment of oxygen isotopic equilibrium, we suggest that diffusion of oxygen occurred through an aqueous fluid phase. The timescale of formation of the oxygen isotopic profile around the wollastonite vein is calculated to be about 0.76 × 10⁶ years using the experimentally determined diffusion constant. Received: 14 January 1997 / Accepted: 23 April 1998  相似文献